|MILESTONE INSECT SPRAY|
|Infosafe™ No.||VARFV||Issue Date||March 2017||Status||ISSUED by MILESTON||BS: 1.17.117|
Classified as hazardous according to criteria of NOHSC
|1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER|
|Product Name||MILESTONE INSECT SPRAY|
|Company Name||Milestone Chemicals Pty. Ltd. (ABN 85115166357)|
|Address||115 Northern Road West Heidelberg|
|Emergency Tel.||(03) 9450 4555 Mon-Fri 8am - 6pm|
|Telephone/Fax Number||Tel: (03) 9450 4555 |
Fax: (03) 9457 5518
|Recommended Use||Insect Spray|
|Other Names||Not Available|
|2. HAZARDS IDENTIFICATION|
|Hazard Classification||Carcinogenicity: Category 2|
Eye Damage/Irritation: Category 2A
Flammable Aerosol: Category 1
STOT Repeated Exposure: Category 1
STOT Single Exposure: Category 1
|Risk Phrase(s)||R12 Extremely Flammable. |
R40(3) Possible risk of irreversible effects.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
|Safety Phrase(s)||S2 Keep out of reach of children. |
S16 Keep away from sources of ignition - No smoking.
S23 Do not breathe gas/fumes/vapour/spray
S24 Avoid contact with skin.
S25 Avoid contact with eyes.
S45 In case of accident or if you feel unwell seek medical advice immediately
S47 Keep at temperature not exceeding 50C
S60 This material and its container must be disposed of as hazardous waste.
S61 Avoid release to the environment. Refer to special instructions/safety data sheet.
S36/37 Wear suitable protective clothing and gloves.
|3. COMPOSITION/INFORMATION ON INGREDIENTS|
|Ingredients determined not to be hazardous||to 100%|
|4. FIRST AID MEASURES|
|First Aid Measures||M|
|Inhalation||Do not breathe vapour. Remove victim to fresh air. Keep victim warm and calm. If patient is unconscious and breathing, place them in the coma position, check airway and observe. Administer oxygen if breathing is difficult. Apply resuscitation if victim is not breathing. Obtain immediate medical care.|
|Ingestion||Do NOT induce vomiting. Give a glass of water to be taken slowly and seek medical advice.|
|Skin||Remove contaminated clothing. Wash area thoroughly with soap and water.|
|Eye||If in eyes, hold eyes open, flood with water for at least 15 minutes and see a doctor.|
|First Aid Facilities||Eye wash station and normal washroom facilities.|
|Advice to Doctor||Product contains a very low proportion of two synthetic pyrethroid insecticides in hydrocarbon solvents. Contact Poisons Information Centre.|
|5. FIRE FIGHTING MEASURES|
|Suitable Extinguishing Media||Small fire: Use water spray, dry chemical or carbon dioxide.|
Large fire: Use water spray or fog.
|Hazards from Combustion Products||Heat or damage to containers can release flammable / poisonous gases.|
Extremely flammable. Pressurised dispenser. Closed containers may rupture
when exposed to heat greater than 50 C. Ruptured containers will rocket.
Released gases can form explosive mixtures with air. Hazardous
concentrations can accumulate in a confined space. Released gases can travel
to source of ignition and flash back. Fire can produce irritating, poisonous and
corrosive gases. Propellant is extremely flammable and heavier than air.
|Special Protective Equipment for fire fighters||High concentration of gas could cause dizziness or asphyxiation without warning. Released gases are harmful. Wear SCBA and protective gloves. If large amounts are involved, wear SCBA and chemical splash suit.|
|Specific Methods||Fight fire from protected position or use unmanned hose holders or monitor nozzles. If safe to do so, move undamaged containers from fire area. Do not approach hot containers. Cool containers with water before handling. If impossible to extinguish fire, protect surroundings, withdraw from are and allow fire to burn.|
|Precautions in connection with Fire||M|
|Unsuitable Extinguishing Media||M|
|6. ACCIDENTAL RELEASE MEASURES|
|Emergency Procedures||Immediately contact police or fire brigade. Spill or leak area should be isolated immediately for at least 8 m in all directions. Eliminate all sources of ignition within at least 15 m. Keep unauthorised personnel away. Keep upwind and to higher ground. When a large quantity is involved in a fire, consider initial evacuation for at least 100 m in all directions. Send message to police and fire brigade. Tell them the location, material, UN Number, quantity and emergency contact as well as damage observed.|
|Spills & Disposal||Eliminate all ignition sources (no smoking, flares, sparks or flame) within at least 15 m. All equipment used when handling the product must be earthed. If water is available, spray leaking containers to reduce ignition hazard and disperse gas. Isolate area until gas has dispersed. Ventilate area. Avoid release to the environment. Do not empty into drains. Absorb in inert absorbent material for disposal by an approved method and / or local regulations.|
|7. HANDLING AND STORAGE|
|Precautions for Safe Handling||Spray in a well ventilated area. Do not breathe vapour. Local exhaust ventilation may be necessary to minimise excessive vapour concentration, if levels are likely to be high or in a confined space. Avoid static charge and discharge with high concentrations and in confined space.|
|Conditions for Safe Storage||Store in a well ventilated area. Pressurised dispenser. Protect from sunlight and do not expose to temperatures exceeding 50 C. Do not pierce or burn this can, even when empty. Store away from corrosive products. Store in accordance with Dangerous Goods Regulations and transport in accordance with the ADG Code for Dangerous Goods Class 2.1|
|8. EXPOSURE CONTROLS/PERSONAL PROTECTION|
|National Exposure Standards||Name||STEL (mgm3)||STEL (ppm)||TWA (mgm3)||TWA (ppm)||FootNote|
|Biological Limit Values||M|
|Other Exposure Information||TLV-STEL: None assigned.|
[NOHSC] - National Occupational Health & Safety Commission (Worksafe Australia)
TWA for Butane is 800ppm
Propane is an asphyxiant
|Engineering Controls||Local exhaust ventilation may be necessary to minimise excessive vapour concentration, if levels are likely to be high or in a confined space.|
|Personal Protective Equipment||Avoid spraying onto eyes and skin. Avoid breathing the vapour. Personal protection to be selected from those recommended below, as appropriate to mode of use, quantity handled and degree of hazard:-|
Goggles, face shield or safety glasses
Gloves, nitrile or high grade PVC
Wear safety glasses and protective gloves. Wear respirator complying with AS1715 and AS1716 if concentration levels are high.
Always maintain a high level of personal hygiene when using this product. That is wash hands before eating, drinking, smoking or using the toilet.
|9. PHYSICAL AND CHEMICAL PROPERTIES|
|Appearance||Aerosol, fine clear spray|
|Solubility in Water||Insoluble|
|Specific Gravity||0.58 approx.|
|pH Value||Not applicable|
|Octanol/Water Partition Coefficient||M|
|Flash Point||-104 to -60°C|
|Flammable Limits - Lower||1.5% in air (v/v)|
|Flammable Limits - Upper||9.6% in air (v/v)|
|Explosion Limit - Upper||M|
|Explosion Limit - Lower||M|
|Other Information||Container under pressure.|
|10. STABILITY AND REACTIVITY|
|Chemical Stability||Stable under normal use conditons. |
|Conditions to Avoid||Heat, flames and sparks. Avoid static charge and discharge with high concentrations and in confined space. Avoid damp conditions.|
|Incompatible Materials||Can react violently with oxidising agents – chlorine, pool chlorine or nitric acid.|
|Hazardous Decomposition Products||Not available.|
|11. TOXICOLOGICAL INFORMATION|
|Inhalation||May cause light-headedness, dizziness and drowsiness. Excessive exposure may cause unconsciousness or even death, due to asphyxiation.|
|Ingestion||Unlikely due to high volatility of product, but is harmful.|
|Skin||May cause cold burn. Irritating to skin.|
|Eye||Liquid will cause severe damage, vapour may irritate.|
|Chronic Effects||No data.|
|Acute Toxicity - Oral||LD 50 : Synthetic pyrethroids 1,000 - 1,244 mg/kg oral, mouse/rat|
|12. ECOLOGICAL INFORMATION|
|Ecotoxicity||Propellant will vapourise rapidly when released to atmosphere. Propellant consists of hydrocarbons that photo chemically decompose under atmospheric conditions.|
|Persistence / Degradability||M|
|Environment Protection||Avoid contaminating waterways, drains, sewers, or ground. |
|13. DISPOSAL CONSIDERATIONS|
|Waste Disposal||Dispose of can by putting in garbage or leaving it at an appropriate metal recycling collection point.|
|Container Disposal||Do not pierce or burn, even when empty.|
|14. TRANSPORT INFORMATION|
|Transport Information||Classified as a Class 2 Dangerous Good. Dangerous Goods of Class 2.1 Flammable Gases, or with a subsidiary risk of 2.1, are incompatible in a placard load with any of the following: - Class 1, Class 3, if both the Class 2.1 and Class 3 dangerous goods are in bulk, Class 4, Class 5, and Class 7. |
|Proper Shipping Name||AEROSOLS|
|Special Precautions for User||Spray in well ventilated area. Keep away from sources of ignition – No smoking.|
Extremely flammable- Do not spray on a naked flame or any incandescent material.
Keep out of reach of children.
|IMDG Marine Pollutant (MP)||M|
|15. REGULATORY INFORMATION|
|Regulatory Information||HAZARDOUS SUBSTANCE.|
Classified as Hazardous according to criteria of National Occupational Health & Safety Commission, Australia (NOHSC).
Classified as a Scheduled Poison according to the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP).
|Hazard Category||Harmful,Extremely Flammable,Dangerous for the environment|
|AICS (Australia)||All components listed. |
|16. OTHER INFORMATION|
|Date of preparation or last revision of MSDS||4/03/2017|
|Literature References||Preparation of Safety Data Sheets for hazardous Chemicals Code of Practice|
Standard for the Uniform Scheduling of Medicines and Poisons
Australian Code for the Transport of Dangerous Goods by Road & Rail
Globally Harmonised System of classification and labelling of chemicals
|Signature of Preparer/Data Service||Technical manager Tel: (03) 9450 4555|
|Technical Contact Numbers||Emergency Advice All Hours:|
Chief Chemist Tel: (03) 9450 4555 Mon-Fri 8am - 6pm
Poisons Information Centre: 13 11 26 - 24hrs
|Other Information||This SDS summarises at the date of issue our best knowledge of the|
health and safety hazard information of the product, and in particular how
to safely handle and use the product in the Workplace. Please refer to the
technical datasheet (Instructions for use), and the label on the drum. The
company cannot anticipate or control the individual working conditions
encountered and so each user should read this SDS carefully, and if in
doubt ring the Contact Point Number given below.
|End of MSDS|
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