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Material Safety Data Sheet


KLEENLINE
Infosafe™ No.VAR9XIssue DateOctober 2016StatusISSUED by MILESTONBS: 1.17.117

Classified as hazardous


 1. Identification

 
GHS Product IdentifierKLEENLINE
 
Company NameMilestone Chemicals Pty. Ltd. (ABN 85115166357)
 
Address115 Northern Road West Heidelberg
VIC 3081
 
Telephone/Fax NumberTel: (03) 9450 4555
Fax: (03) 9457 5518
 
Emergency phone numberPoisons Information Centre Tel 131126
 
Recommended use of the chemical and restrictions on useLiquid beerline cleaner for use strictly in accordance with prescribed instructions issued by consumer's brewery.
 
Other NamesNot Available
 
Other InformationThe information herein is to the best of our knowledge, correct and complete. It describes the safety requirements for this product and should not be construed as guaranteeing specific properties. Since methods and conditions are beyond our control we do not accept liability for any damages resulting from the use of, or reliance on, this information in inappropriate contexts.
 

 2. Hazard Identification

 
GHS classification of the substance/mixtureAcute Toxicity - Oral: Category 4
Eye Damage/Irritation: Category 1
Skin Corrosion/Irritation: Category 1B
 
Signal Word (s)M
 
Hazard Statement (s)H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
 
Precautionary statement – GeneralP102 Keep out of reach of children.
P103 Read label before use.
 
Pictogram (s)M
 
Precautionary statement – Prevention P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash contaminated skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
 
Precautionary statement – Response P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or doctor/physician.
P363 Wash contaminated clothing before reuse.
 
Precautionary statement – Storage P405 Store locked up.
 
Precautionary statement – Disposal P501 Dispose of contents/container: Recycle packaging by replacing cap and
returning clean containers to recycler or designated collection point.
 

 3. Composition/information on ingredients

 
Ingredients    Name CAS Proportion Hazard Statement(s)
   
   Potassium hydroxide1310-58-310-30 %
   Sodium hydroxide1310-73-21-10 %
   Ingredients determined not to be hazardous, including water.to 100%
   Sodium Silicate Solution1344-09-810-30 %
 

 4. First-aid measures

 
InhalationRemove from exposure. Do not use mouth-to-mouth method if victim inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Administer oxygen if breathing is difficult. Obtain immediate medical attention.
 
IngestionImmediately rinse mouth with water. Do NOT induce vomiting. Give a glass of water to be taken slowly. Seek immediate medical attention.
 
SkinRemove all contaminated clothing and immediately wash affected area with plenty of water. If swelling, redness, blistering or irritation occurs, seek medical advice.
 
Eye contactHold eyes open and flood with running water for at least 15 minutes, bathe eyes with soothing eyedrops or sterile saline, urgently seek medical attention. Transport to hospital or medical centre.
 
First Aid FacilitiesEye wash station, safety shower and normal wash room facilities.
 
Advice to DoctorProduct is a mixture containing a moderate proportion of potassium hydroxide. Corrosive by all routes. Risk of serious eye damage. If swallowed, may cause holes in stomach and intestines; gastric lavage may be contraindicated. Treat symptomatically. Contact Poisons Information Centre.
 
Other InformationM
 

 5. Fire-fighting measures

 
Suitable extinguishing mediaUse extinguishing media appropriate to surrounding fire.
 
Unsuitable Extinguishing MediaM
 
Hazards from Combustion ProductsCorrosive or toxic fumes.
 
Specific MethodsIn case of small fire/explosion use water. In case of major emergency use PPE: breathing apparatus and protective gloves.
 
Specific hazards arising from the chemicalNot flammable. Contact with aluminium, tin, zinc or galvanised iron may
generate hydrogen, a flammable gas. Will react vigorously or violently with
acids, generating much heat, and giving off carbon dioxide, a simple
asphyxiant. Contact with ammonium compounds will generate ammonia, a
poisonous gas.
 
Hazchem Code2X
 
Decomposition Temp.M
 
Precautions in connection with FireM
 
Other InformationIf tanks, drums or containers of this material are heated, they may rupture and project corrosive materials over a wide area.
 

 6. Accidental release measures

 
Emergency ProceduresKeep unnecessary people away; Isolate hazard area and deny entry. Stay upwind; Keep out of low areas. Do not walk or touch spilt material unless wearing personal protection as outlined under MSDS. Shut off ignition sources, no flares, smoking or flames in hazard area. Stop leak if you can do it without risk. Water spray may reduce vapour.
 
Spills & DisposalFor large spills:
Contain spillages with sand or earth. Transfer both liquid and solids to suitable container(s). Treat residues as for small spills.
For small spills:
If local regulations permit, mop up with plenty of water and run to waste, diluting greatly with running water. Otherwise, absorb on inert absorbent and transfer to suitable container. Wash site of spillage thoroughly with water and detergent. Ventilate area to dispel any residual vapours.
 

 7. Handling and storage

 
Precautions for Safe HandlingM
 
Conditions for safe storage, including any incompatibilitiesStore in cool place in original container. Store away from oxidisers, acids and foodstuffs. Keep containers closed when not in use. Store out of reach of children. Large quantities should be stored in a bunded area. Do not mix with other chemicals. Clean up all spills and splashes promptly; avoid secondary accidents.
 
Storage RegulationsM
 

 8. Exposure controls/personal protection

 
Occupational exposure limit values     Name STEL (mgm3) STEL (ppm) TWA (mgm3) TWA (ppm) FootNote
Potassium hydroxide2Peak limitation
Sodium hydroxide2Peak limitation
 
Biological Limit ValuesM
 
Appropriate engineering controlsIn very confined spaces have sufficient ventilation. Do not atomise the product. Do not enter confined spaces where vapours may have acculumated. Keep containers closed when not in use. Do not decant in unlabelled bottles. Avoid using aluminium, tin, zinc, galvanised iron, wood or wood products as materials of construction.
 
Respiratory ProtectionM
 
Eye ProtectionM
 
Hand ProtectionM
 
Personal Protective EquipmentThis product is extremely corrosive. Avoid contact with skin and eyes. Avoid breathing aerosols. Recommended personal protection:-
Neoprene or nitrile apron
Neoprene or nitrile.
Chemical goggles or faceshield to protect eyes.
Respirators in accordance with AS/NZS 1715/1716. The use of a P1 respirator with replaceable filters is recommended. Filter capacity and respirator type depends on exposure levels and type of contaminant. If entering spaces where the airborne concentration of a contaminant is unknown then the use of a Self-contained breathing apparatus (SCBA) with positive pressure air supply complying with AS/NZS 1715 / 1716, or any other acceptable International Standard is recommended.
Always maintain a high level of personal hygiene when using cleaning chemicals. That is wash hands before eating, drinking, smoking or using the toilet.
 
Body ProtectionM
 

 9. Physical and chemical properties

 
FormLiquid
 
AppearanceClear, water white liquid.
 
ColourM
 
OdourCaustic like odour
 
Decomposition TemperatureM
 
Melting PointM
 
Boiling Pointapprox. 100C
 
Solubility in WaterMiscible with water in all proportions.
 
Specific Gravity1.4
 
pH12.6-13.0 (1% solution)
 
Vapour PressureM
 
Vapour Density (Air=1)M
 
Evaporation RateM
 
Odour ThresholdM
 
Partition Coefficient: n-octanol/waterM
 
DensityM
 
Flash PointNone
 
FlammabilityNot flammable.
 
Auto-Ignition TemperatureM
 
Flammable Limits - LowerM
 
Flammable Limits - UpperM
 
Explosion Limit - UpperM
 
Explosion Limit - LowerM
 
Kinematic ViscosityM
 
Dynamic ViscosityM
 
Other InformationVery alkaline mixture. Will react vigorously or violently with acids or acidic compounds. Corrodes active metals, such as aluminium, tin or zinc, generating hydrogen, a flammable gas. Contact with ammonium compounds may generate ammonia, a toxic gas. Will absorb carbon dioxide from the air, forming carbonates. May react with organic halogen compounds, especially trichloroethylene. May form shock-sensitive salts with nitro compounds. Will attack wood and wood products. May attack glass on prolonged contact. Slippery when spilled.
 

 10. Stability and reactivity

 
ReactivityM
 
Chemical StabilityStable under normal use conditons.
 
Conditions to AvoidIncompatible materials.
 
Incompatible MaterialsAcids and acidic compounds, active metals, ammonium compounds, glass, nitro compounds, organic halides, wood and paper products.
 
Hazardous Decomposition ProductsEmits choking and corrosive fumes when heated to decomposition.
 
Possibility of hazardous reactionsHydrogen gas is generated when undiluted material contacts aluminium, zinc or tin. May react violently with acids. May generate ammonia from ammonium compounds. May react violently with organic halides. May form shock-sensitive salts with nitro compounds.
 

 11. Toxicological Information

 
Toxicology InformationNo adverse health effects are expected, if the product is handled in accordance with this Material Safety Data Sheet and the product label. Symptoms and effects that may arise if the product is mishandled and overexposure occurs are:
 
Acute Toxicity - OralLD50 Potassium Hydroxide: 273mg/kg oral, rabbit
Sodium Hydroxide: 140-340 mg/kg oral, rat
 
IngestionCorrosive. May cause serious burns to the mouth, throat and gastrointestinal system. May cause a burning pain in the throat and epigastrium, nausea, vomiting, abdominal pains and diarrhoea (occasionally bloody), fall in blood pressure, death. May cause burns and perforation of the stomach and intestines, and the sites of subsequent scaring have been associated with the development of stomach cancer.
 
InhalationWill cause severe irritation to the nose, throat and respiratory system with effects including: Dizziness, headache, coughing, loss of co-ordination, chest pains, respiratory paralysis and or failure.
 
SkinCorrosive to skin - may cause skin burns. Skin contact often does not cause pain, thus care should be taken to avoid contamination of gloves and footwear. Repeated or prolonged contact may lead to irritant contact dermatitis. Mists or aerosols may cause small burns.
 
EyeCorrosive. Risk of serious eye damage, and permanent impairment of sight. May cause redness, pain and blurred vision. Liquid splashes into the eye may rapidly cause severe tissue damage and deep burns.
 
Respiratory sensitisationM
 
Skin SensitisationM
 
Germ cell mutagenicityM
 
CarcinogenicityM
 
Reproductive ToxicityM
 
STOT-single exposureM
 
STOT-repeated exposureM
 
Aspiration HazardM
 
Chronic EffectsLong term, low level exposure can lead to irritation of skin, lungs, nose, throat and mouth. Prolonged or repeated skin contact may lead to necrosis (death) of the skin.
 

 12. Ecological information

 
EcotoxicityThis product is corrosive and poisonous in large concentrations.
 
Persistence and degradabilityReadily biodegradable.
 
MobilityReadily transported by water.
 
Environmental FateThis substance may cause long term adverse effects in the aquatic environment.
 
Bioaccumulative PotentialM
 
Other Adverse EffectsM
 
Environment ProtectionAvoid contaminating waterways, drains, sewers, or ground.
 

 13. Disposal considerations

 
Disposal ConsiderationsM
 
Waste DisposalRefer to appropriate authority in your State. Dispose of material through a licensed waste contractor. Normally suitable for disposal by approved waste disposal agent.
 
Product DisposalAvoid disposal to natural waters or the environment.
 

 14. Transport information

 
Transport InformationClassified as a Class 8 Dangerous Good. Dangerous Goods of Class 8 Corrosives are incompatible in a placard load with any of the following: - Class 1, Class 4.3, Class 5, Class 6, if the Class 6 dangerous goods are cyanides and the Class 8 dangerous goods are acids and Class 7. Store away from acids.
 
U.N. Number3266
 
UN proper shipping nameCORROSIVE LIQUID, BASIC, INORGANIC, N.O.S.
 
Transport hazard class(es)8
 
Hazchem Code2X
 
Special Precautions for UserM
 
Packing GroupII
 
IERG Number37
 
IMDG Marine pollutantM
 
Transport in BulkM
 

 15. Regulatory information

 
Poisons ScheduleS6
 
AICS (Australia)All components listed.
 

 16. Other Information

 
Date of preparation or last revision of SDS17/10/2016
 
Literature ReferencesPreparation of Safety Data Sheets for hazardous Chemicals Code of Practice
Standard for the Uniform Scheduling of Medicines and Poisons
Australian Code for the Transport of Dangerous Goods by Road & Rail
Globally Harmonised System of classification and labelling of chemicals
 
Signature of Preparer/Data ServiceTechnical manager Tel: (03) 9450 4555
 
Technical Contact NumbersEmergency Advice All Hours:
Chief Chemist Tel: (03) 9450 4555 Mon-Fri 8am - 6pm
Poisons Information Centre: 13 11 26 - 24hrs
 
Other InformationThis SDS summarises at the date of issue our best knowledge of the
health and safety hazard information of the product, and in particular how
to safely handle and use the product in the Workplace. Please refer to the
technical datasheet (Instructions for use), and the label on the drum. The
company cannot anticipate or control the individual working conditions
encountered and so each user should read this SDS carefully, and if in
doubt ring the Contact Point Number given below.
 

 End of MSDS

 

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Print Date: 12/11/2019 BS: 1.17.117