| DEOD-A-BOWL |
| Infosafe™ No. | VAR9H | Issue Date | November 2016 | Status | ISSUED by MILESTON | BS: 1.17.117 |
Not classified as hazardous
| 1. Identification | |
| GHS Product Identifier | DEOD-A-BOWL |
| Company Name | Milestone Chemicals Pty. Ltd. (ABN 85115166357) |
| Address | 115 Northern Road West Heidelberg VIC 3081 |
| Telephone/Fax Number | Tel: (03) 9450 4555 Fax: (03) 9457 5518 |
| Emergency phone number | Poisons Information Centre Tel 131126 |
| Recommended use of the chemical and restrictions on use | Highly perfumed cleaner for toilets and urinals. Apply undiluted to bowls, scrub with sanitary brush then flush. |
| Other Names | None Listed |
| Other Information | The information herein is to the best of our knowledge, correct and complete. It describes the safety requirements for this product and should not be construed as guaranteeing specific properties. Since methods and conditions are beyond our control we do not accept liability for any damages resulting from the use of, or reliance on, this information in inappropriate contexts. |
| 2. Hazard Identification | |
| GHS classification of the substance/mixture | Not classified as Hazardous Not classified as a Dangerous Good |
| Signal Word (s) | NONE |
| Hazard Statement (s) | None |
| Precautionary statement – General | P102 Keep out of reach of children. P104 Read Safety Data Sheet before use. |
| Pictogram (s) | None |
| Precautionary statement – Prevention | M |
| Precautionary statement – Response | M |
| Precautionary statement – Storage | P404 Store in a closed container. |
| Precautionary statement – Disposal | P501 Dispose of contents/container: Recycle packaging by replacing cap and returning clean containers to recycler or designated collection point. |
| 3. Composition/information on ingredients | |
| Ingredients | Name | CAS | Proportion | Hazard Statement(s) | ||
| Quaternary Ammonium Compound | 63449-41-2 | 0-5 % | ||||
| Other ingredients determined not to be hazardous, including water | N/A | to 100% | ||||
| Phosphoric acid | 7664-38-2 | 1-10 % | ||||
| 4. First-aid measures | |
| Inhalation | Remove victim to fresh air. Do not use mouth-to-mouth method if victim inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Administer oxygen if breathing is difficult. |
| Ingestion | Rinse mouth with water. Do NOT induce vomiting. Give water to drink to be taken slowly. Seek immediate medical advice. |
| Skin | Remove heavily contaminated clothing. Wash affected area with copious quantities of water for at least 15 minutes. If irritation develops or persists seek medical advice. |
| Eye contact | Immediately irrigate with copious quantities of water for at least 15 minutes. Hold eyelids open. Seek medical attention. |
| First Aid Facilities | Eye wash station and normal washroom facilities. |
| Advice to Doctor | Treat symptomatically for acids (phosphoric acid). |
| Other Information | M |
| 5. Fire-fighting measures | |
| Suitable extinguishing media | Use extinguishing media appropriate to surrounding fire. Use water spray to cool containers and surrounds. |
| Unsuitable Extinguishing Media | M |
| Hazards from Combustion Products | M |
| Specific Methods | Fire-fighters to wear self contained breathing apparatus and protective equipment. If safe to do so remove containers from path of fire. |
| Specific hazards arising from the chemical | Non-flammable liquid. However, flammable and explosive hydrogen gas may be formed on contact with metals. |
| Decomposition Temp. | M |
| Precautions in connection with Fire | M |
| 6. Accidental release measures | |
| Emergency Procedures | Keep unnecessary people away; Isolate hazard area and deny entry. Stay upwind; Keep out of low areas. Wear appropriate eye, skin and respiratory protection as outlined in this MSDS. |
| Spills & Disposal | Wear protective equipment to prevent skin and eye contamination consisting of rubber gloves and safety goggles. Contain large spills with an inert material such as sand, soil or vermiculite. Collect and seal in properly labelled containers for disposal. Small spills may be mopped up. Wash down area with excess water. |
| 7. Handling and storage | |
| Precautions for Safe Handling | M |
| Conditions for safe storage, including any incompatibilities | Store in cool place in sealed plastic containers. Store in a well ventilated area. Store away from oxidising agents and foodstuffs. Store away from sources of heat. Keep containers closed when not in use. |
| Storage Regulations | M |
| 8. Exposure controls/personal protection | |
| Occupational exposure limit values | Name | STEL (mgm3) | STEL (ppm) | TWA (mgm3) | TWA (ppm) | FootNote |
| Phosphoric acid | 3 | 1 | ||||
| Biological Limit Values | M |
| Other Exposure Information | No value assigned by the National Occupational Health and Safety Commission (Worksafe Australia). |
| Appropriate engineering controls | Corrosive liquid. Maintain adequate ventilation at all times. Prevent accumulation of vapours in hollows or sumps. Eliminate any sources of ignition. Exposure to this material may be controlled in a number of ways. The measures appropriate for a particular worksite depend on how the material is used and on the potential for exposure. Engineering methods to prevent or control exposure are preferred. Methods include process or personnel enclosure, mechanical ventilation (dilution and local exhaust), and control of process conditions. If engineering controls and work practices are not effective in preventing or controlling exposure, then suitable personal protective equipment, which is known to perform satisfactorily, should be used. |
| Respiratory Protection | M |
| Eye Protection | M |
| Hand Protection | M |
| Personal Protective Equipment | Avoid contact with the skin and eyes. Avoid breathing the vapour. Personal protection to be selected from those recommended below, as appropriate to mode of use, quantity handled and degree of hazard:- PVC or nitrile rubber gloves. Chemical goggles or faceshield to protect eyes. Respirators in accordance with AS/NZS 1715/1716. The use of a P1 dust mask (disposable) or with replaceable filters is recommended. Filter capacity and respirator type depends on exposure levels and type of contaminant. If entering spaces where the airborne concentration of a contaminant is unknown then the use of a Self-contained breathing apparatus (SCBA) with positive pressure air supply complying with AS/NZS 1715 / 1716, or any other acceptable International Standard is recommended. Always maintain a high level of personal hygiene when using this product. That is wash hands before eating, drinking, smoking or using the toilet. |
| Body Protection | M |
| 9. Physical and chemical properties | |
| Form | Liquid |
| Appearance | Thick blue liquid |
| Colour | M |
| Odour | Floral |
| Decomposition Temperature | M |
| Melting Point | M |
| Boiling Point | M |
| Solubility in Water | Miscible at all concentrations. |
| Specific Gravity | 1.04 |
| pH | 1.5-2.5 (1% solution) |
| Vapour Pressure | M |
| Vapour Density (Air=1) | M |
| Evaporation Rate | M |
| Odour Threshold | M |
| Partition Coefficient: n-octanol/water | M |
| Density | M |
| Flash Point | None |
| Flammability | Non flammable. |
| Auto-Ignition Temperature | M |
| Flammable Limits - Lower | M |
| Flammable Limits - Upper | M |
| Explosion Limit - Upper | M |
| Explosion Limit - Lower | M |
| Kinematic Viscosity | M |
| Dynamic Viscosity | M |
| 10. Stability and reactivity | |
| Reactivity | M |
| Chemical Stability | Stable under normal use conditons. |
| Conditions to Avoid | Heat and incompatibles. |
| Incompatible Materials | Strong bases, aluminium, zinc, magnesium and oxidizing agents. |
| Hazardous Decomposition Products | If involved in a fire, toxic fumes will be evolved. |
| Possibility of hazardous reactions | Contact with metals may produce hydrogen gas which is flammable. If splashing occurs rinse with water and wipe clean. Do not mix with bleaches, acids, or other cleaning solutions. |
| 11. Toxicological Information | |
| Toxicology Information | No adverse health effects are expected, if the product is handled in accordance with this Material Safety Data Sheet and the product label. Symptoms and effects that may arise if the product is mishandled and overexposure occurs are: |
| Acute Toxicity - Oral | LD50: Phosphoric acid: 1530 mg/kg oral, rat Benzalkonium chloride 360 mg/kg oral, rat Surfactants 3,000 mg/kg oral, mouse |
| Ingestion | May cause irritation to mouth, throat and stomach with effects including mucous build up, irritation to the tongue and lips and pains in the stomach, which may lead to nausea, vomiting and diarrhoea. |
| Inhalation | May cause irritation to the nose, throat and respiratory system with effects including: Dizziness, headache and loss of co-ordination. |
| Skin | May cause irritation to the skin, with effects including; Redness and itchiness. |
| Eye | May cause irritation to the eyes, with effects including: tearing, pain, stinging and blurred vision. |
| Respiratory sensitisation | M |
| Skin Sensitisation | M |
| Germ cell mutagenicity | M |
| Carcinogenicity | M |
| Reproductive Toxicity | M |
| STOT-single exposure | M |
| STOT-repeated exposure | M |
| Aspiration Hazard | M |
| Chronic Effects | No prolonged or repeated exposure information is available for this product. |
| 12. Ecological information | |
| Ecotoxicity | Harmful to aquatic organisms. |
| Persistence and degradability | The surfactant used in this product is not considered to be readily biodegradable. |
| Mobility | Readily transported by water. |
| Bioaccumulative Potential | M |
| Other Adverse Effects | M |
| Environment Protection | Avoid contaminating waterways, drains, sewers, or ground. |
| 13. Disposal considerations | |
| Disposal Considerations | M |
| Waste Disposal | Refer to appropriate authority in your State. Dispose of material through a licensed waste contractor. Advise on acidic nature. Normally suitable for disposal by approved waste disposal agent. |
| 14. Transport information | |
| Transport Information | Not classified as a Dangerous Good according to the Australian Code for the Transport of Dangerous Goods by Road and Rail. |
| Special Precautions for User | M |
| IMDG Marine pollutant | M |
| Transport in Bulk | M |
| 15. Regulatory information | |
| Poisons Schedule | Not Scheduled |
| AICS (Australia) | All components listed. |
| 16. Other Information | |
| Date of preparation or last revision of SDS | 20/11/2016 |
| Literature References | Preparation of Safety Data Sheets for hazardous Chemicals Code of Practice Standard for the Uniform Scheduling of Medicines and Poisons Australian Code for the Transport of Dangerous Goods by Road & Rail Globally Harmonised System of classification and labelling of chemicals |
| Signature of Preparer/Data Service | Technical manager Tel: (03) 9450 4555 |
| Technical Contact Numbers | Emergency Advice All Hours: Chief Chemist Tel: (03) 9450 4555 Mon-Fri 8am - 6pm Poisons Information Centre: 13 11 26 - 24hrs |
| Other Information | This SDS summarises at the date of issue our best knowledge of the health and safety hazard information of the product, and in particular how to safely handle and use the product in the Workplace. Please refer to the technical datasheet (Instructions for use), and the label on the drum. The company cannot anticipate or control the individual working conditions encountered and so each user should read this SDS carefully, and if in doubt ring the Contact Point Number given below. |
| End of MSDS | |
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