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Material Safety Data Sheet


CHLOROPHOS
Infosafe™ No.VARCHIssue DateDecember 2016StatusISSUED by MILESTONBS: 1.17.117

Classified as hazardous


 1. Identification

 
GHS Product IdentifierCHLOROPHOS
 
Company NameMilestone Chemicals Pty. Ltd. (ABN 85115166357)
 
Address115 Northern Road West Heidelberg
VIC 3081
 
Telephone/Fax NumberTel: (03) 9450 4555
Fax: (03) 9457 5518
 
Emergency phone numberPoisons Information Centre Tel 131126
 
Recommended use of the chemical and restrictions on useChlorophos is a fast acting germicidal detergent powder specifically formulated for the food processing industry to clean, sanitise and deodorise in one operation.
 
Other NamesNone Listed
 
Other InformationThe information herein is to the best of our knowledge, correct and complete. It describes the safety requirements for this product and should not be construed as guaranteeing specific properties. Since methods and conditions are beyond our control we do not accept liability for any damages resulting from the use of, or reliance on, this information in inappropriate contexts.
 

 2. Hazard Identification

 
GHS classification of the substance/mixtureEye Damage/Irritation: Category 2A
Skin Corrosion/Irritation: Category 2
 
Signal Word (s)M
 
Hazard Statement (s)AUH031 Contact with acids liberates toxic gas.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
 
Precautionary statement – GeneralP102 Keep out of reach of children.
P103 Read label before use.
 
Pictogram (s)M
 
Precautionary statement – Prevention P264 Wash contaminated skin thoroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
 
Precautionary statement – Response P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P332+P313 If skin irritation occurs: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/attention.
P362 Take off contaminated clothing and wash before reuse.
 
Precautionary statement – Storage P404 Store in a closed container.
 
Precautionary statement – Disposal P501 Dispose of contents/container: Recycle packaging by replacing cap and
returning clean containers to recycler or designated collection point.
 

 3. Composition/information on ingredients

 
Ingredients    Name CAS Proportion Hazard Statement(s)
   
   CHLORINATED TRISODIUM PHOSPHATE56802-99-4100%
 

 4. First-aid measures

 
InhalationMove victim to fresh air. Apply resuscitation if victim is not breathing - If trained personnel available administer oxygen if breathing is difficult.
 
IngestionIf swallowed, do NOT induce vomiting. Give a glass of water to be taken slowly. See a doctor.
 
SkinIf dust falls onto the skin, remove any contaminated clothing and wash skin thoroughly with soap and water. If irritation persists see a doctor.
 
Eye contactIf in eyes, hold eyes upen, flood with water for at least 15 minutes and see a doctor.
 
First Aid FacilitiesRecommended: Eye wash. Hand wash basin.
 
Advice to DoctorTreat symptomatically. Contact Poisons Information Centre.
 
Other InformationM
 

 5. Fire-fighting measures

 
Suitable extinguishing mediaWater, or as for other chemicals present.
 
Unsuitable Extinguishing MediaM
 
Hazards from Combustion ProductsDecomposes on heating emitting soot, smoke and decomposition products.
 
Specific MethodsIn case of small fire/explosion use water. In case of major emergency use PPE: breathing apparatus and protective gloves.
 
Specific hazards arising from the chemicalThis material is not a combustible or flammable solid. However, under certain conditions this material, if sufficiently distributed in air and a suitable source of ignition is present, may cause a dust explosion.
 
Decomposition Temp.M
 
Precautions in connection with FireM
 

 6. Accidental release measures

 
Emergency ProceduresM
 
Spills & DisposalAvoid generating dusts. Wear suitable protective equipment. Ventilate area. If possible wet area down to prevent high dust levels. If available, use dustless methods, such as a HEPA vacuum and filter. Otherwise, use a non-sparking shovel and place into a suitably labeled container for later disposal. Do not dry sweep
 

 7. Handling and storage

 
Precautions for Safe HandlingM
 
Conditions for safe storage, including any incompatibilitiesStore in a dry, well ventilated place, out of reach of children. Store in original container. Keep container closed. Keep away from acids. Keep away from oxidising agents. Protect from physical damage. Clean up all spills promptly; avoid secondary accidents.
 
Storage RegulationsM
 

 8. Exposure controls/personal protection

 
Biological Limit ValuesM
 
Appropriate engineering controlsGood industrial hygiene practice requires that employee exposure be maintained below the recommended TLV/TWA. This is preferably achieved through the provision of adequate ventilation where necessary. Where dust cannot be controlled in this way, personal respiratory protection should be employed.
 
Respiratory ProtectionM
 
Eye ProtectionM
 
Hand ProtectionM
 
Personal Protective EquipmentAvoid contact with the skin and eyes. Avoid breathing the dust. Personal protection to be selected from those recommended below, as appropriate to mode of use, quantity handled and degree of hazard:-
Face shield or safety glasses
Gloves, rubber or plastic
Overalls.
The use of a respirator is not normally required, however, if high dust levels are present, then the use of a suitable dust mask or half-face respirator with a P1 filter is recommended. All respirators must comply with AS/NZS 1715 and AS/NZS 1716.
Always maintain a high level of personal hygiene when using cleaning chemicals. That is wash hands before eating, drinking, smoking or using the toilet.
 
Body ProtectionM
 

 9. Physical and chemical properties

 
FormSolid
 
AppearanceWhite free flowing powder
 
ColourM
 
OdourChlorine
 
Decomposition TemperatureM
 
Melting PointNo data.
 
Boiling PointM
 
Solubility in WaterApprox. 20%
 
Specific GravityM
 
pH11.5-12.5 (1% solution)
 
Vapour PressureNone
 
Vapour Density (Air=1)M
 
Evaporation RateM
 
Odour ThresholdM
 
Partition Coefficient: n-octanol/waterM
 
Density0.7 (bulk density)
 
Flash PointNone.
 
FlammabilityNot flammable.
 
Auto-Ignition TemperatureM
 
Flammable Limits - LowerM
 
Flammable Limits - UpperM
 
Explosion Limit - UpperM
 
Explosion Limit - LowerM
 
Kinematic ViscosityM
 
Dynamic ViscosityM
 

 10. Stability and reactivity

 
ReactivityM
 
Chemical StabilityStable under normal use conditons.
 
Conditions to AvoidIncompatibles.
 
Incompatible MaterialsStrong acids, alkalis and oxidizing agents.
 
Hazardous Decomposition ProductsDecomposes on heating emitting soot, smoke and decomposition products.
 
Possibility of hazardous reactionsM
 

 11. Toxicological Information

 
Toxicology InformationNo adverse health effects are expected, if the product is handled in accordance with this Material Safety Data Sheet and the product label. Symptoms and effects that may arise if the product is mishandled and overexposure occurs are:
 
Acute Toxicity - OralNo data
 
IngestionMay cause irritation to mouth, throat and stomach with effects including mucous build up, irritation to the tongue and lips and pains in the stomach, which may lead to nausea, vomiting and diarrhoea.
 
InhalationMay cause irritation to the nose, throat and respiratory system with effects including: Dizziness, headache and loss of co-ordination.
 
SkinWill cause irritation to the skin, with effects including; Redness, itchiness, and possible dermatitis.
 
EyeWill cause irritation to the eyes, with effects including: tearing, pain, stinging and blurred vision. Depending upon duration of exposure, eye damage may occur.
 
Respiratory sensitisationM
 
Skin SensitisationM
 
Germ cell mutagenicityM
 
CarcinogenicityM
 
Reproductive ToxicityM
 
STOT-single exposureM
 
STOT-repeated exposureM
 
Aspiration HazardM
 
Chronic EffectsProlonged or repeated skin contact may lead to dermatitis.
Prolonged or repeated exposure or deliberately concentrating and inhaling the vapour(s) may result in lung function incapacity or death.
 

 12. Ecological information

 
EcotoxicityNot severe
 
Persistence and degradabilityInherently biodegradable
 
MobilityPowder is easily contained, but material is reasonably soluble in large amounts of water.
 
Bioaccumulative PotentialM
 
Other Adverse EffectsM
 
Environment ProtectionAvoid contaminating waterways, drains, sewers, or ground.
 

 13. Disposal considerations

 
Disposal ConsiderationsM
 
Waste DisposalRefer to appropriate authority in your State. Dispose of material through a licensed waste contractor. Normally suitable for disposal by approved waste disposal agent.
 

 14. Transport information

 
Transport InformationNot classified as a Dangerous Good according to the Australian Code for the Transport of Dangerous Goods by Road and Rail.
 
Special Precautions for UserM
 
IMDG Marine pollutantM
 
Transport in BulkM
 

 15. Regulatory information

 
Poisons ScheduleNot Scheduled
 
AICS (Australia)All components listed.
 

 16. Other Information

 
Date of preparation or last revision of SDS5/12/2016
 
Literature ReferencesPreparation of Safety Data Sheets for hazardous Chemicals Code of Practice
Standard for the Uniform Scheduling of Medicines and Poisons
Australian Code for the Transport of Dangerous Goods by Road & Rail
Globally Harmonised System of classification and labelling of chemicals
 
Signature of Preparer/Data ServiceTechnical manager Tel: (03) 9450 4555
 
Technical Contact NumbersEmergency Advice All Hours:
Chief Chemist Tel: (03) 9450 4555 Mon-Fri 8am - 6pm
Poisons Information Centre: 13 11 26 - 24hrs
 
Other InformationThis SDS summarises at the date of issue our best knowledge of the
health and safety hazard information of the product, and in particular how
to safely handle and use the product in the Workplace. Please refer to the
technical datasheet (Instructions for use), and the label on the drum. The
company cannot anticipate or control the individual working conditions
encountered and so each user should read this SDS carefully, and if in
doubt ring the Contact Point Number given below.
 

 End of MSDS

 

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Print Date: 12/11/2019 BS: 1.17.117